Response to the review comments on “Soil fluxes of carbonyl sulfide (COS), carbon monoxide, and carbon dioxide in a boreal forest in southern Finland”

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Soil is a major contributor to the biosphere–atmosphere exchange of carbonyl sulfide (COS) and carbon monoxide (CO). COS is [..1 ]a tracer to quantify terrestrial photosynthesis based on the [..2 ]coupled leaf uptake of COS and [..3 ]CO2, but [..4 ]such use requires separating soil COS flux[..5 ], which is unrelated to photosynthesis, from ecosystem COS uptake. For CO, soil is a [..6 ]significant natural sink that influences the tropospheric CO budget. [..7 ]In the boreal forest, magnitudes and variabilities of soil COS and CO fluxes remain poorly understood. We measured hourly 5 soil fluxes of COS, CO, and CO2 [..8 ]over the 2015 late growing season (July to November) in a Scots pine forest in Hyytiälä, Finland. The soil acted as a net sink of COS and CO[..9 ], with average uptake rates around 3 pmol m−2 s−1 for COS [..10 ]and 1 nmol m−2 s−1 for CO, respectively. Soil respiration showed seasonal dynamics controlled by soil temperature, peaking [..11 ]at around 4 μmol m−2 s−1 [..12 ]in late August and September and dropping to 1–2 μmol m−2 s−1 in October. In contrast, seasonal variations of COS and CO fluxes were weak and mainly driven by 10 soil moisture changes through diffusion limitation. COS and CO fluxes did not appear to respond to temperature, although they both correlated well with soil respiration in specific temperature bins. [..13 ]However, COS : CO2 and 1removed: used to improve constraints on 2removed: link between 3removed: of 4removed: this use requires the 5removed: to be well quantified 6removed: main sink in natural environments 7removed: We measured 8removed: hourly 9removed: . Average uptake rates were 10removed: , 11removed: in late August and September with fluxes 12removed: and 13removed: We found that COS:CO2 and CO:CO2 flux ratios were modulated by temperature, possibly indicating

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Response to the comments on “Soil fluxes of carbonyl sulfide (COS), carbon monoxide, and carbon dioxide in a boreal forest in southern Finland”

Soil is a major contributor to the biosphere–atmosphere exchange of carbonyl sulfide (COS) and carbon monoxide (CO). COS is a tracer to quantify terrestrial photosynthesis based on the coupled leaf uptake of COS and CO2, but such use requires separating soil COS flux, which is unrelated to photosynthesis, from ecosystem COS uptake. For CO, soil is a significant natural sink that influences the ...

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Interactive comment on “Soil fluxes of carbonyl sulfide (COS), carbon monoxide, and carbon dioxide in a boreal forest in southern Finland” by Wu Sun et al

This study provides much-needed in situ measurements of the soil fluxes of COS and CO. Both are important trace gases for chemistry & climate impacts and as tracers for photosynthesis and anthropogenic activity, respectively. The data set is relatively rich, despite some significant gaps, and interesting trends in diurnal and seasonal patterns and relationships with environmental drivers are ob...

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Interactive comment on “Soil fluxes of carbonyl sulfide (COS), carbon monoxide, and carbon dioxide in a boreal forest in southern Finland” by Wu Sun et al

This study provides much-needed in situ measurements of the soil fluxes of COS and CO. Both are important trace gases for chemistry & climate impacts and as tracers for photosynthesis and anthropogenic activity, respectively. The data set is relatively rich, despite some significant gaps, and interesting trends in diurnal and seasonal patterns and relationships with environmental drivers are ob...

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Litter dominates surface fluxes of carbonyl sulfide in a Californian oak woodland

Carbonyl sulfide (COS) is a promising tracer for partitioning terrestrial photosynthesis and respiration from net carbon fluxes, based on its daytime co-uptake alongside CO2 through leaf stomata. Because ecosystem COS fluxes are the sum of plant and soil fluxes, using COS as a photosynthesis tracer requires accurate knowledge of soil COS fluxes. At an oak woodland in Southern California, we mon...

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The flux of carbonyl sulfide and carbon disulfide between the atmosphere and a spruce forest

Turbulent fluxes of carbonyl sulfide (COS) and carbon disulfide (CS2) were measured over a spruce forest in Central Germany using the relaxed eddy accumulation (REA) technique. A REA sampler was developed and validated using simultaneous measurements of CO2 fluxes by REA and by eddy correlation. REA measurements were conducted during six campaigns covering spring, summer, and fall between 1997 ...

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تاریخ انتشار 2017